Oz and James return to the opulent Napa Valley. James is dismayed that Cabernet is a trophy to be paraded here, rather than a wine to be drunk and enjoyed. But at Bill Harlan's estate, a vinery making fine wines that regularly get ratings of 100/100, he concedes that he may have become a wine snob. As they drive home in the now-battered RV, they discuss where their next adventure will take them.
They meet Mike Benziger, owner of an organic estate. He maintains an insectry, where he breeds insects to eat the lesser bugs that damage his vines, and a sceptical James is silenced when he tastes the wine. Next, they visit the Gallo estate, a producer of affordable wines that flood the international market. Their hostess, Gina Gallo, is charming, but Oz and James sour her hospitality by having another argument.
Arriving at the glamorous Napa Valley, they are dismayed to discover that they're staying in the car park. The pair argue about who will empty the RV's waste tank, then sample Californian champagne at the Tattinger estate. Next, the Schramsberg estate, where the quarreling continues with a heated debate about what bubbles taste like. Frustrated, James rents a Mustang Shelby to get them out of the hated RV.
Oenophile Oz Clarke takes novice James May around California's wineries. They have arrived in the Santa Cruz area. Tension mounts between the odd couple when James crashes the RV. The bickering continues at Randall Grahm's New World vinery, which produces what James sees as yet more over-priced, inaccessible wine. James gets his revenge when they go to meet 'two-buck-Chuck', whose wine factory churns out bottles for only two dollars.
Oenophile Oz Clarke takes novice James May on a month-long trip around California's wineries. In this third episode, Oz and James are on the coastline of Monterey County. All manner of non-wine tasting related activities ensue, including muscle car racing and rifle shooting with an eccentric millionaire.